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This limitation arises primarily because the BBB restricts the accessibility of antioxidant compounds to the central nervous system, thereby preventing sustained therapeutic concentrations required to confer antioxidant effects in chronic neurodegenerative conditions [237]

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Clinical, Cosmetic and Investigational Dermatology, 10, 147-153

The clinical relevance is straightforward

AD, for instance, has been associated with elevated levels of glutamate, which may enhance NMDAR signaling by modulating the receptor itself [213]