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Detection of the hydrolysis of acetanilide by minipig microsomes demonstrates sensitivity to amides which are hydrolysed at low levels in humans in vivo

doi: 10.1093/ajcn/77.2.326 359 ChuCJiangJYuLLiYZhangSZhouWet al

The second difficulty arises from the fact that carboxylic acids and 1 or 2-amines do not form amide bonds on mixing, but will generally react by proton transfer to give salts (the intermolecular equivalent of zwitterion formation)

If you typically experience mild nausea or reduced appetite and suddenly those effects disappear after a storage incident, that could indicate degradation

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